Journal
CHEMPHYSCHEM
Volume 14, Issue 4, Pages 661-673Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201200801
Keywords
aggregation; hydrogen bonds; polymerization; self-assembly; supramolecular chemistry
Funding
- JNCASR
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An understanding of the mechanisms of supramolecular polymerization from a molecular point of view is lacking. Several reports in the literature on the mechanism exhibited by different classes of molecules are examined in an attempt to correlate the molecular features to the aggregation pathway followed. It is proposed that long-range interactions between oligomers could lead to their cooperative growth. The lack thereof leads to isodesmicity.
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