Journal
CHEMPHYSCHEM
Volume 13, Issue 11, Pages 2795-2800Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201200021
Keywords
chromophores; conjugation; solvent effects; symmetry-breaking; two-photon absorption
Funding
- Iranian Ministry of Science, Research and Technology
- University of Parma
- INSTM
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A four essential-state model is proposed for a detailed description of optical spectra of a family of anionic polymethine dyes. Extensive spectroscopic data from the literature are quantitatively described within a model that accounts for non-adiabatic electron-vibration coupling and for polar solvation.
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