Journal
CHEMPHYSCHEM
Volume 12, Issue 12, Pages 2207-2215Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201100129
Keywords
nanoparticles; oxides; phase equilibria; surface energy; thermodynamics
Funding
- U.S. Department of Energy
- National Science Foundation
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Because different solid materials (phases) have different surface energies, equilibria among them will be significantly affected by particle size. This Minireview summarizes experimental (calorimetric) data for the surface energies of oxides and discusses shifts in the stability of polymorphs, the thermodynamics of hydration, and oxidation-reduction reactions in nanoscale oxide systems.
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