Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 10, Pages 3092-3096Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201410996
Keywords
elimination; halogenation; heterocycles; palladium; synthetic methods
Categories
Funding
- NSFC [21472042]
- Fundamental Research Funds for the Central Universities
- Fok Ying-Tong Education Foundation for Young Teachers in the Higher Education Institutions of China [131011]
- NCET [12-0851]
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Although the advances on carbon halide reductive elimination have been made, the alkyl bromide and chloride analogues remain a challenge. Here, a palladium(0)-catalyzed iminohalogenation of ,-unsaturated oxime esters is described, and the use of electron-poor phosphine ligands proved to be crucial to promoting alkyl bromide and chloride reductive elimination. Furthermore, S(N)2-type alkyl bromide and chloride reductive elimination has also been established.
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