Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 54, Issue 35, Pages 10178-10182Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201504109
Keywords
frustrated Lewis pairs; hydrogenation; Lewis acids; alkenes; phosphorus
Categories
Funding
- NSERC of Canada
- Canada Research Chair
- Alexander von Humboldt Foundation
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The combination of phosphorus(V)-based Lewis acids with diaryl amines and diaryl silylamines promotes reversible activation of dihydrogen and can be further exploited in metal-free catalytic olefin hydrogenation. Combined experimental and density functional theory (DFT) studies suggest a frustrated Lewis pair type activation mechanism.
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