Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 14, Issue 10, Pages 1647-1650Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201801105
Keywords
C-60 complex; calixarenes; coupling reactions; void space; selenium
Categories
Funding
- JSPS KAKENHI [20438120, 16K17871]
- Kitasato Research Center for Environment Science
- Grants-in-Aid for Scientific Research [16K17871] Funding Source: KAKEN
Ask authors/readers for more resources
An efficient cyclization toward a cyclic tetramer of dithienothiophene (DTT) linked by divalent selenium atoms has been developed via palladium-catalyzed coupling reaction of (nBu(3)Sn)(2)Se. X-ray analysis revealed its highly symmetrical structure had an alternate arrangement of DTT units. There are several Se interactions forming a supramolecular network leading to large void channel space. The cyclic tetramer possesses moderate electron-donating ability. Furthermore, the cyclic tetramer undergoes complexation with C-60 in a 1:2 ratio in the solid state to give a highly symmetrical three-dimensional array of C-60.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available