Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 9, Issue 4, Pages 950-971Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201301582
Keywords
catalytic oxidations; hypervalent iodine; oxidants; rearrangement; stereoselective reactions
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Funding
- European Union
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Hypervalent iodine chemistry is now a well-established area of organic chemistry. Novel hypervalent iodine reagents have been introduced in many different transformations owing to their mild reaction conditions and environmentally friendly nature. Recently, these reagents have received particular attention because of their applications in catalysis. Numerous hypervalent iodine-catalyzed oxidative functionalizations such as oxidations of various alcohols and phenols, -functionalizations of carbonyl compounds, cyclizations, and rearrangements have been developed successfully. In these catalytic reactions stoichiometric oxidants such as mCPBA or oxone play a crucial role to generate the iodine(III) or iodine(V) species in situ. In this Focus Review, recent developments of hypervalent iodine-catalyzed reactions are described including some asymmetric variants. Catalytic reactions using recyclable hypervalent iodine catalysts are also covered.
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