Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 9, Issue 10, Pages 2720-2734Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201402109
Keywords
asymmetric catalysis; cycloaddition; organocatalysis; phosphines; zwitterions
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Funding
- Shanghai Municipal Committee of Science and Technology [11JC1402600]
- National Basic Research Program of China (973 Program) [2010CB833302]
- National Natural Science Foundation of China [20472096, 20872162, 20672127, 21121062, 20732008, 21372241, 21302203, 21361140350, 21102166, 21372250]
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Chiral phosphines are versatile Lewis basic catalysts that are capable of promoting a wide range of asymmetric reactions. In particular, recently designed chiral phosphines based on the concept of bi-/multifunctionality have been demonstrated to be effective catalysts for many types of asymmetric reactions, such as (aza)-MBH reactions, cycloaddition reactions, and nucleophilic addition reactions. This short overview summarizes the recent advances in this field and highlights the most-significant achievements.
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