Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 9, Issue 5, Pages 1247-1251Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201400067
Keywords
benzocarborane; biphenyl; carboranes; electron-deficient compounds; p-terphenyl
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Funding
- Japan Society for the Promotion of Science [24655102, 24102013]
- Japan Society for the Promotion of Science for Young Scientists [12J03404]
- Grants-in-Aid for Scientific Research [24655102] Funding Source: KAKEN
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The synthesis and properties of biphenyl- and p-terphenyl-fused o-carboranes are described. Aryl rings in the biphenyl and p-terphenyl skeletons are highly coplanar because of the presence of the o-carborane unit. o-Carborane exhibits an electron-withdrawing character via the inductive effect, resulting in a decrease in both the HOMO and LUMO levels of oligophenyls without causing electronic perturbation.
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