Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 9, Issue 9, Pages 2568-2575Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201402242
Keywords
arenes; doping; graphitic carbon; palladium; sumanene
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Funding
- Japan Society for the Promotion of Science [22245007, 22685006]
- Japan Science and Technology Agency [A-STEP] [AS2211281D]
- Japan Science and Technology Agency [ACT-C]
- JSPS
- Grants-in-Aid for Scientific Research [14J00723, 22245007] Funding Source: KAKEN
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Sumanenemonoone imine compounds bridged by a redox-active pi-conjugated unit on the basis of the conversion between 1,4-phenylenediamine and 1,4-benzoquinonediimine were synthesized and characterized. The stepwise coordination of the imino groups to Pd-II in the sumanenemonoone imine compound bridged by 1,4-benzoquinonediimine was indicated by the titration experiment. Laser irradiation of a film of the metal-free quione-diimine gave nitrogen-doped graphitic carbon, which was supported by an increase in conductivity and by Raman spectroscopy. The obtained graphitic carbon corresponds to carbonous compounds thermally treated at approximately 700-1000 degrees C. The ratio of nitrogen and carbon relative to that in the starting compound was nearly completely retained (5.4% decrease).
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