Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 8, Issue 8, Pages 1879-1885Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201300147
Keywords
metal-organic frameworks; porous materials; supercapacitors; template synthesis; zeolites
Categories
Funding
- New Star Program of the Beijing Committee of Science and Technology [2012004]
- National Basic Research Program of China [2009CB939902]
Ask authors/readers for more resources
Three types of zeolitic imidazolate frameworks (ZIFs) with different topological structures and functional imidazolate-derived ligands, namely, ZIF-8, ZIF-68, and ZIF69, have been directly carbonized to prepare porous carbon materials at 1000 degrees C. These as-synthesized porous carbon materials were activated with fused KOH to increase their surface areas and pore volumes for use in gas storage and supercapacitors. The relationship between the local structure of the products and the composition of the precursors has been investigated in detail. The BET surface areas of the resultant activated carbon materials are 2437 (CZIF8a), 1861 (CZIF68a), and 2264m2g-1 (CZIF69a). CZIF8a exhibits the highest H2-storage capacities of 2.59wt.% at 1atm and 77K, whereas CZIF69a has the highest CO2 uptake of 4.76mmolg-1 at 1atm and 273K, owing to its local structure and pore chemical environment. The specific capacities are calculated from the CV curves. CZIF69a exhibits the highest supercapacitor performance of 168Fg-1 at a scan speed of 5mVs-1. These results indicate that the functional chloride group on the benzimidazolate ligand plays a very important role in improving the surface area, pore volume, and, therefore, CO2-capture and supercapacitor properties of the corresponding porous carbon materials.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available