Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 7, Issue 8, Pages 1744-1754Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201200211
Keywords
arenes; copper; homogeneous catalysis; palladium; trifluoromethylation
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Funding
- state of Mecklenburg-Vorpommern
- Bundesministerium fur Bildung und Forschung (BMBF)
- Max-Buchner Research Foundation
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Aryl-CF3 as an extremely important family of fluorinated organic compounds holds wide applications in pharmaceuticals, agrochemicals, and advanced materials. Traditionally, such trifluoromethylated compounds have been synthesized from the corresponding aryl trichlorides via Cl exchange reactions (Scheme 1). This Focus review gives an overview over the recent development of trifluoromethylation of (hetero)arenes.
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