Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 7, Issue 3, Pages 565-571Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201100757
Keywords
batteries; electrospinning; lithium; nanofibers; nanostructures
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Funding
- National Basic Research Program of China [2009CB939901]
- National Natural Science Foundation of China [90922016, 10979047, 11079004]
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Hierarchical LiV3O8 nanofibers, assembled from nanosheets that have exposed {100} facets, have been fabricated by using electrospinning combined with calcination. The formation mechanism of hierarchical nanofibers was investigated by X-ray diffraction and scanning electron microscopy. Poly(vinyl alcohol) (PVA) played a dual role in the formation of the nanofibers: besides acting as the template for forming the fibers, it effectively prevented the aggregation of LiV3O8 nanoparticles, thereby allowing them to grow into small nanosheets with exposed {100} facets owing to the self-limitation property of LiV3O8. This nanostructure is beneficial for the insertion/extraction of lithium ions. Meanwhile, the {100} facets have fewer and smaller channels, which may effectively alleviate proton co-intercalation into the electrode materials. Hence, the hierarchical LiV3O8 nanofibers exhibit higher discharge capacities and better cycling stabilities as the anode electrode material for aqueous lithium-ion batteries than those reported previously. We demonstrate that these hierarchical nanofibers have promising potential applications in aqueous lithium-ion batteries.
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