Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 6, Issue 9, Pages 2419-2425Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201100244
Keywords
Diels-Alder reaction; dynamic covalent libraries; fluorescence; reversible reactions; supramolecular chemistry
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Funding
- Centre National de la Recherche Scientifique (CNRS)
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A series of readily accessible, dynamic Diels-Alder reactions that are reversible at room temperature have been developed between anthracene derivatives as dienes and N-phenyl-1,2,4-triazoline-3,5-dione as the dienophile. The adducts formed undergo reversible component exchange to form dynamic libraries of equilibrating cycloadducts. Furthermore, reversible adduct formation allows temperature-dependent modulation of the fluorescent properties of anthracene components; a feature of potential interest for the design of optodynamic polymeric materials by careful selection and manipulation of these simple dienes and dienophiles.
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