4.6 Article

Facile Preparation of Homo- and Hetero-Dimetallic Complexes with a 4-Phosphino-Substituted NHC Ligand. Toward the Design of Multifunctional Catalysts

Journal

CHEMISTRY-AN ASIAN JOURNAL
Volume 6, Issue 4, Pages 1099-1103

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201000856

Keywords

carbenes; copper; gold; palladium; phosphines

Funding

  1. NIH [R01 GM 68825]
  2. DOE [DE-FG02-09ER16069]

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A series of bimetallic complexes have been synthesized that are supported by a 4-phosphino-substituted NHC ligand. The use of this stable ligand reduces the number of synthetic steps and allows for a wide range of metal combinations to be introduced into the complexes.

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