Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 6, Issue 2, Pages 621-627Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201000624
Keywords
gold; esterification; heterogeneous catalysis; neighboring-group effects; oxidation
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Funding
- Japan Society of the Promotion of Science (JSPS)
- ERATO (JST)
- NEDO
- GCOE
- Grants-in-Aid for Scientific Research [22750032] Funding Source: KAKEN
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Aerobic oxidation of aldehydes to 1,2- and 1,3-diol monoesters was catalyzed by polymer-incarcerated gold nanoclusters under ambient conditions. The esterification proceeded much faster with 1,2- and 1,3-diols and their derivatives rather than with methanol.
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