Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 4, Issue 8, Pages 1184-1195Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.200900080
Keywords
asymmetric catalysis; chiral ligands; functionalization; ionic liquids; organocatalysis
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Funding
- Natural Science Foundation of China [20421202, 20632060, 20702052]
- Ministry of Science and Technology [2008CB617501]
- Chinese Academy of Sciences
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By judiciously anchoring functional groups onto chiral ionic liquids, functionalized chiral ionic liquids (FCILs) are emerging as a new type of asymmetric organocatalysts and nonclassical chiral ligands. This Focus Review highlights the applications of FCILs from the viewpoint of asymmetric catalysis. We focus mainly on the de novo designed and synthesized FCILs which likely still maintain the typical ionic liquids properties, and in a few cases relevant ionic liquid immobilized chiral catalysts are briefly discussed.
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