Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 4, Issue 4, Pages 508-518Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.200800378
Keywords
cycloaddition; asymmetric catalysis; axial chirality; biaryls; transition metals
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Funding
- Asahi Glass Foundation
- Uchara Memorial Foundation
- Naito Foundation
- Japan Science and Technology Agency
- MEXT Japan [20675002, 19350046]
- Takasago International Corporation
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Recent advances towards a development of novel transition-metal-catalyzed enantioselective [2+2+2] cycloadditions for the synthesis of axially chiral biaryls are reviewed. A number of efficient enantioselective biaryl syntheses were accomplished by chiral cobalt(I), iridium(I), and rhodium(I) complex catalyzed [2+2+2] cycloadditions. Furthermore, the enantioselective synthesis of axially chiral biaryls possessing non-biaryl axial chirality was also developed by using chiral rhodium(I) complexes as catalysts.
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