Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 4, Issue 11, Pages 1712-1716Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.200900238
Keywords
aldehydes; anisidine; organocatalysis; palladium; Saegusa reaction
Categories
Funding
- National Natural Science Foundation of China [90813005]
- 863 Hi-Tech Program of China [2006AA020404]
- China 111 Project [B07023]
- Shanghai Ministry of Science and Technology [07A14013]
Ask authors/readers for more resources
An o-anisidine-Pd(OAc)(2) catalytic system for the direct co-catalytic Saegusa oxidation of beta-aryl substituted aldehydes to alpha,beta-unsaturated aldehydes has been developed. The use of o-anisidine in place of (S)-diphenylprolinol made the process more simply and cost-effective. The process not only features the use of unmodified aldehydes rather than enol silyl ethers, but also gives moderate to good yields (44-72%)
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
