Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 4, Issue 2, Pages 294-301Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.200800312
Keywords
alkynes; cyclization; dimerization; double homologation; zirconium
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A double homologation method for the formation of substituted soluble pentacenes was developed by a zirconium-mediated cyclization of tetrayne derivatives. Thermal dimerization of tetra- and octasubstituted pentacenes was observed. The dimerization behavior was observed to be strongly related to the substituent groups affixed to the pentacenes.
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