Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 24, Issue 58, Pages 15663-15668Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201803433
Keywords
carbon; iron; nanostructures; reduction; sol-gel processes
Categories
Funding
- National Natural Science Foundation of China [51702046, 51772050, 51432004, 51702091]
- Innovation Program of Shanghai Municipal Education Commission [2017-01-07-00-03-E00025]
- Shanghai Committee of Science and Technology, China [17ZR1401000, 16JC1401800, 18JC1411200]
- Shanghai Pujiang Program [17PJ1400100]
- State Key Laboratory of Pollution Control and Resource Reuse Foundation [PCRRF17005]
- Natural Science Foundation of Hubei Province, China [2017CFB192]
- State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University
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All-in-one architectures in which uniform nanoscale zero-valent iron nanoparticles are wrapped in hollow porous carbon shells are highly desirable for environmental applications such as wastewater treatment and for use as catalysts, but their preparation remains a significant challenge. Herein, a spatially confined strategy for the in situ preparation of uniform Fe-0@mC (mC=micro/mesoporous carbon) yolk-shell nanospheres, in which the iron nanoparticles are encapsulated in thin, porous carbon shells, is reported. The elaborately designed Fe-0@mC yolk-shell nanospheres were obtained by utilizing silica- and phenolic-resin-coated magnetite nanoparticle core-shell structures as templates by means of selective etching and in situ thermal reduction. The highly dispersed iron nanoparticles with superior reduction capability can effectively remove metal pollutants (e.g., Au-III, Ag-I, and Cu-II), the carbon shell acts as protective cover and prevents aggregation of iron nanoparticles, and the void space in the capsules serves as a reactor for reduction and catalytic reactions.
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