Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 25, Issue 10, Pages 2396-2406Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201803150
Keywords
bonding; dinuclear complexes; electronic structure; ferrocene; M-M interactions
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Funding
- University of Stuttgart, Department of Inorganic Chemistry
- German Research Foundation (DFG) [INST 40/467-1 FUGG]
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Ligands with 1,1'-bis(donor)ferrocene motif are capable of a wide range of binding modes, including the trans chelation mode in which there is a Fe-M interaction (kappa(3)-D,Fe,D), in the form of a dative Fe -> TM bond (TM=transition metal). This Minireview will explore the nature of this Fe-TM interaction thorough select examples as well as how to characterize a Fe -> TM dative bond using physical, computational, and spectroscopic techniques.
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