Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 24, Issue 65, Pages 17205-17209Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201804157
Keywords
difunctionalization of alkenes; electrochemistry; green method; radical migration; sulfonylation
Categories
Funding
- National Natural Science Foundation of China [21472082, 21772085, 21761132021]
Ask authors/readers for more resources
An efficient electrochemical 1,2-sulfonylation/alkynylation of alkenes via radical 1,4-alkynyl migration of alkynyl-substituted tertiary alcohols is described, which used sodium sulfinates as sulfonyl sources affording the corresponding alpha-sulfonyl-beta-alkynylated products in moderate to excellent yields. This electrochemical reaction proceeds smoothly without the use of any metal catalyst, additive and oxidant and thus represents a new and eco-friendly strategy for the difunctionalization of unactive olefins, and also the first example of the electrochemical distal radical migration reaction.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available