4.6 Review

Cobalt-Pincer Complexes in Catalysis

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 25, Issue 1, Pages 122-143

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201803016

Keywords

(de)hydrogenation; bond formation; homogeneous catalysis; cobalt; pincer complex; transfer hydrogenation

Funding

  1. State of Mecklenburg-Western Pomerania
  2. BMBF
  3. DFG
  4. ERC

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Non-noble metal catalysts based on pincer type compounds are of special interest for organometallic chemistry and organic synthesis. Next to iron and manganese, currently cobalt-pincer type complexes are successfully applied in various catalytic reactions. In this review the recent progress in (de)hydrogenation, transfer hydrogenation, hydroboration and hydrosilylation as well as dehydrogenative coupling reactions using cobalt-pincer complexes is summarised.

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