Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 25, Issue 12, Pages 2927-2934Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201803413
Keywords
actinides; f-block elements; neptunium; organometallic; plutonium
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Funding
- Joint Research Centre Funding Source: Medline
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Recent developments and results from the organometallic chemistry of the actinides are reviewed. In the last one and a half years the structural data of about 15organometallic complexes of transuranium actinides (Np or Pu) have been published, all involving -ligands in the coordination sphere of the metal ion. On the basis of these data, a comparison of these molecules is presented. Depending on the steric demands of the ligands, effects like the actinide contraction seem to be stronger or weaker in the structural features. This indicates that the interplay between the actinide ion and the -ligand is rather flexible, enabling the formation of stable bonds over a broad range of actinide ion oxidation states.
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