Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 25, Issue 10, Pages 2407-2422Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201803803
Keywords
C-Si bond formation; Si-Si activation; silicon; silylation; transition metals
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Funding
- National Natural Science Foundation of China [21622202, 21502125]
- National Science and Technology Major Project of the Ministry of Science and Technology of the People's Republic of China [2017ZX09101003-005-004]
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Disilanes possessing a Si-Si bond are unique element-element species. Transition-metal-catalyzed activation of the Si-Si bond allows many useful transformations that generate diverse organosilanes. This Minireview highlights impressive developments in this field over the past decade, with an emphasis on the formation of vinyl-, aryl-, and acylsilanes by C(sp(2))-Si bond formation as well as the formation of allyl- and alkylsilanes by C(sp(3))-Si bond formation.
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