Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 24, Issue 55, Pages 14639-14643Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201803863
Keywords
anisotropy; cage compounds; dielectric permittivity; ferroelectricity; polar order
Categories
Funding
- SERB, India [EMR/2016/000614]
- Nanomission Project, DST, India [SR/NM/TP-13/2016]
Ask authors/readers for more resources
Designing molecular crystals with switchable dipoles for ferroelectric applications is challenging and often serendipitous. Herein, we show a systematic approach toward hierarchical 1D, 2D and 3D frameworks that are assembled through successive linkage of metal-organic cages [Cu-6(H2O)(12)(TPTA)(8)](12+) with chloride ions. Their ferroelectric properties are due to the displacement of channel-bound nitrate counterions and solvated water molecules relative to the framework of cages. Ferroelectric measurements of crystals of discrete and 1D-framework assemblies showed axial ferroelectric anisotropy with high remnant polarisation. Both, the reversible formation of cage-connected networks and the observation of ferroelectric anisotropic behaviour are rare among metal-ligand cage assemblies.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available