Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 24, Issue 50, Pages 13093-13097Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201802630
Keywords
chain structures; charge transfer; donor-acceptor systems; electron transfer; magnetic properties
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [16H02269]
- Japan Society for the Promotion of Science (JSPS) [2601, JP17H05137]
- E-IMR project
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A new ionic donor-acceptor (D(+)A(-)) chain compound, [{Ru-2(2,6-(CF3)(2)PhCO2)(2)(p-PhPhCO2)(2)}DMDCNQI] (1; 2,6-(CF3)(2)PhCO2- = 2,6-bis(trifluoromethyl)benzoate; p-PhPhCO2- = 4-biphenylcarboxylate; DMDCNQI = 2,5-dimethyl-N,N'-dicyanoquinonediimine) was isolated and structurally characterized. It represents the first of this type of ionic chain compounds.
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