Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 16, Pages 4542-4547Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304798
Keywords
carbonylation; homogeneous catalysis; oxygen; palladium; solvent effects
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Funding
- EPSRC [EP/E011179/1]
- Loughborough University
- Axel Wenner-Gren sabbatical scholarship
- COST through the ORCA action
- EPSRC [EP/E011179/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/E011179/1] Funding Source: researchfish
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A mild protocol has been developed for the Pd-II-catalyzed alkoxycarbonylation of terminal olefins to produce ,-unsaturated esters with a wide range of substrates. Key features are the use of MeCN as solvent (and/or ligand) to control the reactivity of the intermediate Pd complexes and the combination of CO with O-2, which facilitates the Cu-II-mediated reoxidation of the Pd-0 complex to Pd-II and prevents double carbonylation.
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