4.6 Article

Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 14, Pages 3874-3886

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304823

Keywords

dual catalysis; photocatalysis; radical reactions; single-electron transfer; visible light

Funding

  1. European Research Council under the European Community [25936]
  2. Deutsche Forschungsgemeinschaft [SFB 858]
  3. NRW Graduate School of Chemistry
  4. Alexander von Humboldt Foundation

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The photoredox activation of organic substrates with visible light is a powerful methodology that generates reactive radical species under very mild conditions. When combined with another catalytic process in a dual catalytic system, novel, visible-light-promoted transformations have been realized that do not proceed using either catalyst in isolation. In this minireview, the state of the art in organic reactions mediated by dual catalytic systems merging photoredox activation with organo-, acid or metal catalysis is discussed.

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