Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 38, Pages 12032-12036Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201404310
Keywords
carboboration; copper; cross-coupling; palladium; synergistic catalysis
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Funding
- Indiana University
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A synergistic Pd/Cu system for the coupling of alkenes, (Bpin)(2) (pin=pinacolate), and aryl/vinyl bromides is disclosed. This method allows for the catalytic generation of secondary Csp(3)-Cu nucleophiles in situ and subsequent Pd-catalyzed cross-coupling.
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