Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 15, Pages 4227-4231Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201303989
Keywords
amine; hydrogenation; nitrile; P; N ligands; ruthenium
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Funding
- State of Mecklenburg-Western Pomerania
- BMBF
- DFG
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A convenient and efficient catalyst system for the hydrogenation of aliphatic nitriles towards the corresponding primary amines in high to excellent yields is presented. In addition, aromatic nitriles are reduced smoothly, too. The use of low catalyst loadings and molecular hydrogen make this protocol an attractive methodology.
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