Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 34, Pages 10636-10639Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201402935
Keywords
alkylidenecyclopropanes; allenes; catalysis; gold; sulfonium ylides
Categories
Funding
- University of Vienna
- DFG [MA 4861/4-1, MA 4861/4-2]
- Fundacao para a Ciencia e Tecnologia [PEst-OE/QUI/UI0100/2011, PTDC/QUI-QUI/099389/2008]
- Fundação para a Ciência e a Tecnologia [PTDC/QUI-QUI/099389/2008] Funding Source: FCT
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A stereoselective gold(I)-catalyzed intermolecular cyclopropanation of allenamides with stabilized sulfonium ylides is reported. This transformation enables the direct synthesis of diacceptor alkylidenecyclopropanes and proceeds under very mild conditions through allene activation.
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