Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 30, Pages 9246-9249Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201403083
Keywords
bromosilylenes; dibromodisilenes; N-heterocyclic carbenes; reaction mechanisms; silyliumylidenes
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Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan [24109013, 24109003, 25109543, 25288021, 23685010, 25102519, 2408, 2401]
- Molecular Systems Research project of RIKEN Advanced Science Institute
- Grants-in-Aid for Scientific Research [24109013, 25109543, 25288021, 24109003, 25102519, 26620051] Funding Source: KAKEN
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Reactions of stable 1,2-dibromodisilenes ((E)-Ar(Br) Si=Si(Br)Ar) with N-heterocyclic carbenes (NHC) afforded NHC-arylbromosilylene adducts or bromide salts of the corresponding bis-NHC adducts of the formal arylsilyliumylidene cations ([ArSi:](+)). In some cases, an NHC was able to replace a bromide anion in the coordination sphere of the arylbromosilylene-NHC adduct.
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