Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 30, Pages 9230-9233Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201402871
Keywords
cross-linking; curing; photochemistry; poly(dimethylsiloxane); silicon
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Funding
- Danish Agency for Science, Technology and Innovation
- Danish National Advanced Technology Foundation
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To overcome the drawbacks exhibited by platinum-catalyzed curing of silicones, photoinitiated thiol-ene cross-linking of high-molecular-weight poly(dimethylsiloxane) (PDMS) prepolymers has been investigated as a pathway to novel soft PDMS networks, based on commercially available starting materials was developed. Through a fast and efficient two-step cross-linking reaction highly flexible PDMS elastomers were prepared.
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