Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 44, Pages 14164-14176Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201403453
Keywords
reactivity; reduction; sulfoxylate; thiourea oxides
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Funding
- National Natural Science Foundation of China [51221462]
- Jiangsu province Natural Science Foundation [BK20131111]
- Fundamental Research Funds for the Central Universities [2013 K05]
- PAPD
- Chinese-Hungarian cooperative grant [K-TET-CN-1-2012-0030]
- Romanian Ministry for Education and Research [PCE 488/2012]
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Thiourea dioxide is one of the best known, important, and stable products of thiourea oxidation. This compound has long been considered as an effective reducing agent for many years. Traditional areas of its application include the textile and paper industries. In recent years, however, thiourea dioxides and trioxides have been widely used in new fields including organocatalytic, polymerization, and phase-transfer reactions; reduction of graphene and graphite oxides; bitumen modifications; synthesis of guanidines and their derivatives; and studying nonlinear dynamical phenomena in chemical kinetics. The review gives a detailed survey of the latest developments and main trends in the chemistry and application of thiourea mon-, di-, and trioxides.
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