Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 50, Pages 16458-16461Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201405143
Keywords
amines; binol; chirality; enantioselective fluorescent sensors; zinc
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Funding
- US National Science Foundation [CHE-0717995]
- National Program on Key Basic Research Project of China (973 Program) [2012CB720603, 2013CB328900]
- National Science Foundation of China [21232005, 21321061, J1310008, J1103315]
- Specialized Research Fund for the Doctoral Program of Higher Education in China
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A 1,1'-bi-2-naphthol (BINOL)-based chiral aldehyde in combination with Zn-II shows a highly enantioselective fluorescent response toward functional chiral amines at lambda > 500 nm. However, the combination of salicylaldehyde and Zn-II gives the same fluorescent enhancement for both enantiomers of a functional chiral amine at lambda = 447 nm. By using the fluorescent responses of the combination of the BINOL-based chiral aldehyde, salicylaldehyde and Zn-II at the two emission wavelengths, both the concentration and enantiomeric composition of functional chiral amines such as amino alcohols, diamines, and amino acids can be simultaneously determined by a single fluorescent measurement. This work provides a simple and convenient method for chiral assay.
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