Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 41, Pages 13113-13116Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201404762
Keywords
cyclization; diamination; hypervalent iodine; organocatalysis; stereoselective synthesis
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Funding
- EU Marie Curie fellowship (DIALMEC) [298642]
- Erasmus program
- Commonwealth Scholarship Commission in the United Kingdom
- School of Chemistry, Cardiff University
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A new chiral thiohydantoin catalyst is used for the stereoselective iodoamination of alkenes. N-iodosuccinimide as the source of the electrophilic iodine is activated by catalytic amounts of different additives which also influence the regioselectivity of some cyclizations.
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