Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 26, Pages 7931-7934Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201402520
Keywords
carboxylation; flow chemistry; lithiation; mass transfer; microreactors
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Funding
- Taiyo Nippon Sanso
- [2105]
- Grants-in-Aid for Scientific Research [26288049] Funding Source: KAKEN
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Carboxylation of short-lived organolithiums bearing electrophilic functional groups such as nitro, cyano, and alkoxycarbonyl groups with CO2 to give carboxylic acids and active esters was accomplished in a flow microreactor system. The successful reactions indicate that gas/liquid mass transfer and the subsequent chemical reaction with CO2 are extremely fast.
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