Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 13, Pages 3616-3620Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304615
Keywords
boration; density functional theory; diboron reagents; nucleophilic boron
Categories
Funding
- Spanish Ministerio de Economia y Competitividad (MINECO) [CTQ2010-16226, CTQ2008-06549-C02-01/BQU]
- Direccio General de Recerca (DGR) of the Autonomous Government of Catalonia [2009SGR462, XRQTC]
- URV
Ask authors/readers for more resources
Activating the non-symmetrical BpinBdan diboron reagent with alkoxide leads to the formation of two possible adducts: MeO(-)BpinBdan or MeO(-)BdanBpin. Experimental and theoretical investigation confirms that the MeO(-)Bpin interaction is preferred and thus selective formation of a CBdan bond upon reaction with an activated CC bond.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
