Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 16, Pages 4548-4553Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304978
Keywords
alkylation; -amino esters; arylation; CH activation; palladium catalysis
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Funding
- Monbusho (The Ministry of Education, Culture, Sports, Science and Technology)
- Japan Science and Technology Agency
- Grants-in-Aid for Scientific Research [22105002] Funding Source: KAKEN
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The palladium-catalyzed arylation/alkylation of ortho-CH bonds in N-benzoyl -amino ester derivatives is described. In such a system both the NH-amido and the CO2R groups in the -amino ester moieties play a role in successful CH activation/CC bond formation using iodoaryl coupling partners. A wide variety of functional groups and electron-rich/deficient iodoarenes are tolerated. The yields obtained range from 20 to 95%.
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