Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 45, Pages 14868-14871Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201404229
Keywords
alkynes; furans; gold catalysis; imines; sulfonamides
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Funding
- China Scholarship Council (CSC)
- Heinz Gotze Memorial Fellowship program of the Athenaeum Foundation fellowship
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A variety of N-(furan-3-ylmethylene)benzenesulfonamides were obtained by a gold(I)-catalyzed cascade reaction from easily accessible starting materials. The reaction pathway involves a rarely observed 1,2-alkynyl migration onto a gold carbenoid. This observation further enriches gold carbenoid chemistry with regard to group migration.
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