4.6 Article

Visible-Light-Induced C - S Bond Activation: Facile Access to 1,4-Diketones from β-Ketosulfones

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 11, Pages 3045-3049

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304898

Keywords

-ketosulfones; CS bond activation; 1; 4-diketones; radicals; visible light

Funding

  1. National Natural Science Foundation of China (NSFC) [21232003, 21202053]
  2. National Basic Research Program of China [2011CB808603]

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A novel method for the synthesis of 1,4-diketones from -ketosulfones was developed by means of a visible light-induced CS bond activation process. Symmetrical and unsymmetrical 1,4-diketones can be easily prepared in moderate to good yields.

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