4.6 Article

Carbonate Linkage Bearing Naphthalenediimides: Self-Assembly and Photophysical Properties

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 16, Pages 4537-4541

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201304857

Keywords

excimer; naphthalene diimide; photophysics; self-assembly; supramolecular polymers

Funding

  1. JNCASR
  2. DST, Government of India
  3. Sheikh Saqr Career Award Fellowship

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Self-assembly of carbonate linkage bearing naphthalene diimides (NDI) showed unusually red-shifted excimer emission at approximately 560nm. On the other hand, the ether linkers showed usual excimers at around 520nm, highlighting the role of the carbonate group in tuning the molecular organization and the resultant photophysical properties of NDI.

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