Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 48, Pages 15732-15736Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201404859
Keywords
C-H activation; heterobicyclic alkenes; hydroarylation reaction; rhodium; sulfoximines
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Funding
- China Scholarship Council
- Alexander von Humboldt Foundation
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Rhodium-catalyzed directed CH-functionalizations have been used in hydroarylations of heterobicyclic alkenes with NH-sulfoximines. Unexpectedly, the bicyclic framework is retained, resulting in the formation of addition products being attractive intermediates for functionalized molecules that are difficult to prepare by other means.
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