Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 32, Pages 9910-9913Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201403891
Keywords
cyclization; diamination; hypervalent iodine; organocatalysis; stereoselective synthesis
Categories
Funding
- EU [298642]
- ENCPB
- School of Chemistry, Cardiff University
- Engineering and Physical Sciences Research Council [1250128, EP/J00569X/1] Funding Source: researchfish
- EPSRC [EP/J00569X/1] Funding Source: UKRI
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Vicinal diamines constitute one the most important functional motif in organic chemistry because of its wide occurrence in a variety of biological and pharmaceutical molecules. We report an efficient metal-free, highly stereoselective intramolecular diamination using a novel chiral hypervalent iodine reagent together with its application as an efficient catalyst for the synthesis of diamines.
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