Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 46, Pages 15000-15004Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201405119
Keywords
alkenylation; CH activation; decarboxylation; fluoroalkenes; heterocycles; palladium
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Funding
- INSA Rouen [ANR-11-LABX-0029]
- Rouen University [ANR-11-LABX-0029]
- CNRS EFRD [ANR-11-LABX-0029]
- Labex SynOrg [ANR-11-LABX-0029]
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Pd/Cu-catalyzed decarboxylative/direct CH alkenylations of heteroarenes with -fluoroacrylic acid is reported. This method offers step-economical and stereocontrolled access to valuable heteroarylated monofluoroalkenes as both Z and E isomers, which are known to be useful in the synthesis of fluorinated biomolecules.
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