Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 22, Pages 6613-6617Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201402218
Keywords
1; 3-enyenes; alkenes; allenes; cobalt; cyclobutene
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Funding
- MEXT [25708018, 23105546]
- Asahi Glass Foundation
- Japan Society for the Promotion of Science (JSPS)
- Grants-in-Aid for Scientific Research [25708018] Funding Source: KAKEN
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Cobalt-catalyzed cross-dimerization of simple alkenes with 1,3-enynes is reported. A [2+2] cycloaddition reaction occurred, with alkenes bearing no allylic hydrogen, by reductive elimination of a (3)-butadienyl cobaltacycle. On the other hand, aliphatic alkenes underwent 1,4-hydroallylation by means of exo-cyclic -H elimination. These reactions can provide cyclobutenes and allenes that were previously difficult to access, from simple substrates in a highly chemo- and regioselective manner.
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