Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 19, Pages 5555-5558Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201400296
Keywords
absolute configuration; chirality; Coulomb explosion imaging; deuterium; glyceraldehyde
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Funding
- Ruprecht-Karls Universitat Heidelberg
- Max-Planck Society
- NASA
- NSF
- ERC [StG 307163, StG 258740]
- Weizmann Institute through the Joseph Meyerhoff program
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The absolute configuration of (R,R)-2,3-dideuterooxirane, which has been independently determined using Coulomb explosion imaging, has been unambiguously chemically correlated with the stereochemical key reference (+)-glyceraldehyde. This puts the absolute configuration of D(+)-glyceraldehyde on firm experimental grounds.
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