Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 20, Issue 7, Pages 1829-1833Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201303807
Keywords
electrocatalysis; electrodeposition; mesoporous materials; polyaniline; silica mesochannels
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Funding
- National Nature Science Foundation of China [21222504, J1210042]
- Program for New Century Excellent Talents in University
- Fundamental Research Funds for the Central Universities [2013FZA3006]
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A mesoporous silica film (MSF) with vertically oriented mesochannels on a conductive substrate serves as a hard-template for electrodeposition of polyaniline (PANI). The PANI nanostructures thus prepared are orderly confined in silica mesochannels, eventually producing a robust hybrid film. The film displays a good electrocatalytic activity toward oxidation of ascorbic acid, and can be used for potentiometric pH sensing with a Nernstian response.
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